@ChrisGendy
 Jyväskylä, Suomi
Joined February 2013
  • Tweets232
  • Following358
  • Followers148
9Media
Now formatted and looking glorious! ✨ Thanks again to the whole team for the great work 😁
Angewandte Chemie@angew_chem30 Jun 2023
T-shaped Ni0 Systems Featuring Cationic Tetrylenes: Direct Observation of L/Z-type Ligand Duality, and Alkene Hydrogenation Catalysis (Terrance J. Hadlington and co-workers) @DrHadlington @aenney19 @philkeil1 @lapluhp @TU_Muenchen #openaccess #projektDEAL ow.ly/hJ7i50P18Pw

T‐shaped Ni0 Systems Featuring Cationic Tetrylenes: Direct Observation of L/Z‐type Ligand Duality,...

Cationic low-coordinate tetrylenes are shown to behave as Z-type ligands towards Ni0, forming rare T-shaped Ni0 complexes. These selectively bind classical N-bases at EII (E=Ge, Sn), which switches...

onlinelibrary.wiley.com
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Replying to @Chemjobber
Does driving into Canadian Customs by mistake with, among others, 30 mL P(SiMe3)3, and being asked to open the Schlenk tube so the agent could smell it count? No? Flying internationally with 4L 65% alcohol plum brandy in the carry-on luggage?
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A Planar Nickelaspiropentane Complexes with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation pubs.acs.org/doi/10.1021/jac…

A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and...

Abstract. The nature of transition-metal–olefin bonding has been explained by the Dewar–Chatt–Duncanson model within a continuum of two extremes, namely, a

pubs.acs.org
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Chris Gendy retweeted
Pickle
@mpickle27 Jul 2022
If you sleep less than 7 hours a night, read this:
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Pawel Löwe@PawelLoewe22 Jul 2022
Thanks to everybody who attended my talk on Thursday at the #ICOMC2022. I am really grateful for all the valuable discussions during and after the session.
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A Pd(0) nitrene? Not yet certain, but there is indication... For more than 3 years in the making, happy to have it finally out. Congrats to all! 💥🔝💥🔝🌟🥳👏🎉#3min_lifetime #IR_absorption #CHactivation #CFactivation @djanamchlle @mgimferrer #happynette pubs.acs.org/doi/10.1021/jac…

Palladium Terminal Imido Complexes with Nitrene Character

Abstract. Whereas triplet-nitrene complexes of the late transition metals are isolable and key intermediates in catalysis, singlet-nitrene ligands remain e

pubs.acs.org
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Chris Gendy retweeted
Fabian Dankert@danke2t21 Dec 2021
Christian @hering_lab and I reviewed the chemistry of heavier group13/15 multiple bond systems. You might want to give it a read if you are interested in synthesis, structure and reactivity of main-group multiple bonds. pubs.rsc.org/en/content/arti…

Heavier group 13/15 multiple bond systems: synthesis, structure and chemical bond activation

Heavier group 13/15 multiple bonds have been under investigation since the late 80s and to date, several examples have been published, which shows the obso

pubs.rsc.org
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For #NHC chemists, a bis(CAAC) is now available through the beautiful ligand design and synthetic execution by @UofC_Science's Braulio Puerta and Ethan Pezoulas, with @Alex_Harrison, @ZackDubrawski, B. Gelfand, @Roope_Suvinen & H. Tuononen @uniofjyvaskyla. pubs.rsc.org/en/content/arti…

Bis[cyclic (alkyl)(amino)carbene] isomers: Stable trans-bis(CAAC) versus facile olefin formation...

Isomeric bis(aldiminium) salts with a 1,4-cyclohexylene framework were synthesized. The first isolable bis(CAAC) was prepared from the trans-stereoisomer a

pubs.rsc.org
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#Science
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Chris Gendy retweeted
Pawel Löwe@PawelLoewe28 Apr 2022
I'm delighted to speak at the @Fusion_Conf 4th Small Molecule Activation Conference #SMA2022 in Cancún next month! Looking forward to my first in-person conference since two years and presenting parts of the final project of my doctoral studies.
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Now nicely typeset! As a few people have asked offline, here's a size comparison that, in retrospect, we probably should have put into the paper. Our 4-way PN cage connector opens up the parameter space between adamantanes and tetraarylmethanes.
Angewandte Chemie@angew_chem26 Apr 2022
(PNSiMe3)4(NMe)6: A Robust Tetravalent Phosphaza-adamantane Scaffold for Molecular and Macromolecular Construction (Chitnis) @chitnislab onlinelibrary.wiley.com/doi/…
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Our paper “Binding methane to a metal centre” is now available in Nature Chemistry (link below). This is the first publication to come out of my PhD and hopefully there will be many more to come! #organometallics #NMR #methane ⁦@NatureChemistry⁩ nature.com/articles/s41557-0…
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Our latest work is online in @angew_chem - a new air stable, geometrically rigid, 4-way connector. 31P NMR galore, kinetics, a pretty structure, P/Ti rich materials, DFT & more! Congrats to PhD student @JoeBedard_ on his 1st paper with us! @DalhousieChem onlinelibrary.wiley.com/doi/…

(PNSiMe3)4(NMe)6: A Robust Tetravalent Phosphaza‐adamantane Scaffold for Molecular and Macromolec...

The synthesis of a new air-stable and thermally robust tetrahedral tetravalent inorganic cage, (PNSiMe3)4(NMe)6 has been achieved. This cage allows four-fold functionalization reactions on its...

onlinelibrary.wiley.com
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Delighted to announce that our new paper has just been published in Nature Communications! Congratulations to Weifan, Fiona, and Yosuke for their amazing teamwork. We never stop extending the pi-surface of azabuckybowls. nature.com/articles/s41467-0…
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I'm super excited and grateful to have been selected for the Dr John Kendall Doctoral Thesis Award from the @UofC_Science for presenting and defending the best doctoral thesis in the Faculty of Science for 2020-2021. This would not have been possible without the support (1/2)
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Pleasant surprise this morning, @ChrisGendy's study of cyclo-P4 bonding and dynamic in #nickel complexes incorporating a chelating bis(#NHC) is now typeset. @UofC_Science
Angewandte Chemie@angew_chem10 Mar 2022
Haptotropism in a Nickel Complex with a Neutral, pi-Bridging cyclo-P4 Ligand Analogous to Cyclobutadiene (Tuononen) @uniofjyvaskyla @RolandRoesler @ChrisGendy #openaccess onlinelibrary.wiley.com/doi/…
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Haptotropism in a Nickel Complex with a Neutral, pi-Bridging cyclo-P4 Ligand Analogous to Cyclobutadiene (Tuononen) @uniofjyvaskyla @RolandRoesler @ChrisGendy #openaccess onlinelibrary.wiley.com/doi/…
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There goes the ole “nickel is cheap” sales pitch. ☠️ rip nickel chemists everywhere.
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Excited to share my #RSCPoster which explores the Anionic Pathway in the Nickel-Catalysed Cross-Coupling of Aryl Ethers! #RSCInorg #RSCCat @EvaHeviaGroup @DCBPunibern
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