@Inordanic

Synthetic inorganic chemist. @Royalcom1851 Research Fellow at @UCLChemistry

 London, UK
scholar.google.com/citations?user=o_t0xYwAAAAJ&hl=en
Joined January 2014
  • Tweets24
  • Following89
  • Followers98
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I'm going to be migrating over to bluesky (once I figure out how to use it), feel free to find me over there: @inordanic.bsky.social
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Just out 😊: @SiadWolff has accomplished the design of a molecule with a Ni-CO2-Fe entity, resembling the one in the enzyme CODH, giving us a clue why nature may have used iron here. Thanks a lot also to all other contributors!! @angew_chem @UniSysCat onlinelibrary.wiley.com/doi/…
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📢 We have a PhD position available in our lab exploring main group compounds and their reactivity. We are very happy for people to contact us with informal enquires! kcl.ac.uk/study-legacy/fundi….
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New Hot article from Daniel Wilson (@inordanic), Caroline Knapp (@cazknapp) and colleagues at @UCLChemistry 'Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane' 🔥 #OpenAccess 🔓 pubs.rsc.org/en/content/arti…

Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane†

The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic invest

pubs.rsc.org
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New comment in @NatRevChem with @FieldenStephen 🥳 We discuss our experiences navigating academia while having a long-term chronic illness - Multiple Sclerosis. Let’s continue on our positive trend to empower academics with disabilities! Hope you enjoy reading our article ☺️
Stephen Fielden@FieldenStephen25 Oct 2024
Pleased to see this comment nature.com/articles/s41570-0… published, where @ANBismillah and I discuss our experiences of living with multiple sclerosis (MS) and working in academia. Free to access link here: rdcu.be/dX6Xc @NatRevChem

Holding your nerve in academia whilst managing multiple sclerosis

Nature Reviews Chemistry - Multiple sclerosis (MS) is a degenerative disease of the central nervous system. Two early-career researchers in supramolecular chemistry share their experiences of...

nature.com
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Jingyan's thermodynamic study on CO2 binding to an N-heterocyclic imine is fresh off the press @ChemCommun This is also my first project from @UCLChemistry 🥳 with @cazknapp tinyurl.com/2v2he9nz

Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane†

The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic invest

pubs.rsc.org
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A nickel(0) complex inserts into an oxidized [4Fe-4S] cluster, giving iron−nickel−sulfur clusters that provide insight into the potential properties of the C cluster of CO dehydrogenase enzymes NEW #ASAP by @patholland_0, Serena DeBeer & team Read here: go.acs.org/bcK
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One for the nickel-heads: We use redox miss-match to insert nickel into iron-sulfur cubanes, resulting in some cool clusters (including one with four 3-coordinate metals!). Another step closer to the C cluster... Out in ACS central science: tinyurl.com/4dk7yv9t
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Congratulations to Trevor, Nick & Joy @BetleyGroup @HarvardCCB 🥳🥳 pubs.acs.org/doi/10.1021/jac… @J_A_C_S #crystllography #education

High-Spin [FeI3] Cluster Capable of Pnictogen Atom Capture

Abstract. Using a new hexanucleating anildophosphine ligand tBuLH3 (1,3,5-C6H9(NHC6H3–5-F–2-P(tBu)2)3), the all-monovalent [FeI3] compound (tBuL)Fe3 (1) wa

pubs.acs.org
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A big congratulations to Nadia Stephaniuk for her prize poster on bimetallic enzyme mimics! @Inordanic @kclchemistry
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Check out our newest paper out now in @J_A_C_S, dealing with cooperative sulfur transformations at a dinickel site. Congratulations to Dr. Valeria Tagliavini and a huge thank you to all authors for their contributions 🎊🎊🎊 tinyurl.com/25kzmjd8 – at Göttingen, Germany
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Our first paper on ACS models is live in @J_A_C_S. NHCs being as trusty as ever, we find that Ni1+ can bind CO and convert it into thioesters, just like the enzyme! Excited to see where this new project goes with @ra_musgrave @RoesslerGroup pubs.acs.org/doi/10.1021/jac…

Mixed Valence {Ni2+Ni1+} Clusters as Models of Acetyl Coenzyme A Synthase Intermediates

Abstract. Acetyl coenzyme A synthase (ACS) catalyzes the formation and deconstruction of the key biological metabolite, acetyl coenzyme A (acetyl-CoA). The

pubs.acs.org
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A special shout out to the Yale contingent (Reagan Hooper, Patrick Holland, Majed Fataftah) for the invaluable assistance and discussions ❤️! You can read a highlight of the work here tinyurl.com/fe64j5yy
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An isolable phosphinidene oxide, you ask? That’s right!!! Check out Chenyang’s (@Chenyang__Hu) outstanding work out today in @NatureChemistry! Using steric bulk to help stabilise a highly reactive P(III)=O bond. nature.com/articles/s41557-0…
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Dan Wilson retweeted
Top Science
@isciverse6 Jul 2024
A Sterically Accessible Monomeric Stibine Oxide Activates Organotetrel(IV) Halides, Including C–F and Si–F Bonds @J_A_C_S #Chemistry #Chemed #Science #TechnologyNews #news #technology #AcademicTwitter #ResearchPapers #InnoConf24 pubs.acs.org/doi/10.1021/jac…
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Dan Wilson retweeted
Jupp Lab@JuppLab24 Jun 2024
PhD advert 📢 We have some last minute PhD funding available to start in October 2024 to work in main group chemistry and catalysis. Please share with anyone who might be interested and contact me directly (unfortunately UK funding only) @UoBChemistry
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Many congrats to Ana McGinley & @MantingMu for their work on Alkene Isomerisation Catalysed by a Superbasic Sodium Amide just off the press @angew_chem! Another fantastic collaboration with @antorna, Gian Luca Righetti @EvaHeviaGroup! Great teamwork!!👏🥳 doi.org/10.1002/anie.2024072…

Alkene Isomerisation Catalysed by a Superbasic Sodium Amide

Using superbasic sodium amide NaTMP as a catalyst, isomerisation of alkenes at room temperature under mild condition has been accomplished. Isolation of organometallic intermediates and DFT calcula...

onlinelibrary.wiley.com
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🥳🎉Really excited! you can now read about the fun we have been having with lasers💥, x-rays 🩻 and magnets 🧲 to study photochemistry ☀️🧪 pubs.acs.org/doi/10.1021/jac… thanks to @SPike_Chem @DiamondLightSou @DominikJKubicki !

Photoinitiated Single-Crystal to Single-Crystal Redox Transformations of Titanium-Oxo Clusters

Abstract. Titanium-oxo clusters can undergo photochemical reactions under UV light, resulting in the reduction of the titanium-oxo core and oxidation of su

pubs.acs.org
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Reductive Retrocyclization of a Mangana(II)cyclopentasilane to Form Manganese(0) Bis(eta2-disilene) Complexes (Yusuke Sunada and co-workers) #OpenAccess onlinelibrary.wiley.com/doi/…

Reductive Retrocyclization of a Mangana(II)cyclopentasilane to Form Manganese(0) Bis(η2‐disilene)...

Mangana(II)cyclopentasilanes were transformed into manganese(0) bis(η2-disilene) complexes via a retrocyclization induced by ligand exchange. An XPS analysis revealed the formation of a zero-valent...

onlinelibrary.wiley.com
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Phosphorus-Ligand Redox Cooperative Catalysis: Unraveling Four-Electron Dioxygen Reduction Pathways and Reactive Intermediates | Journal of the American Chemical Society @CHNsci #Phosphorus #Redox #Catalysis #Oxygen #Reduction pubs.acs.org/doi/10.1021/jac…

Phosphorus-Ligand Redox Cooperative Catalysis: Unraveling Four-Electron Dioxygen Reduction Pathways...

Abstract. The reduction of dioxygen to water is crucial in biology and energy technologies, but it is challenging due to the inertness of triplet oxygen an

pubs.acs.org
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