@LhfaShen
 Toulouse, France
lhfa.cnrs.fr/index.php/equipes/shen
Joined March 2020
  • Tweets29
  • Following46
  • Followers114
2Media
September is there with the start of a new academic year... A good time to have a look back on the achevements of 2022-2023. Congratulation to Raphaël @RavelMassol and Sandip @Munshi_SM17 doi.org/10.1002/chem.2023021…

One Ligand to Bind them All: S~C~S2− Carbon‐ and Sulfur‐Based Gem‐Dianion as Structuring Ligand for...

Bis-(diphenylthiophosphinoyl)methanediide dianion (SCS)2− is an ideal platform for the building of polymetallic iron assemblies in which the same carbon and sulfur environment is maintained upon...

chemistry-europe.onlinelibrary.wiley.com
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September is there with the start of a new academic year... A good time to have a look back on the achievements of 2022-2023. Congrats to @NebraNoel doi.org/10.1039/D3SC02001K

Scrutinizing formally NiIV centers through the lenses of core spectroscopy, molecular orbital...

Nickel K- and L2,3-edge X-ray absorption spectra (XAS) are discussed for 16 complexes and complex ions with nickel centers spanning a range of formal oxida

pubs.rsc.org
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September is there with the start of a new academic year... A good time to have a look back on the achievements of 2022-2023, Congrats to @LucaJDemonti, Daniel @jovensancho1 and Hana Tabikh doi.org/10.1002/ejic.2023000… doi.org/10.1002/ejic.2023000… doi.org/10.1039/D3CC00493G

Safe Entry to Ag(I)/Ag(III) Mixed Valence Salts Containing the Homoleptic Ag(III) Anion [Ag(CF3)4]−

A family of AgI/AgIII mixed valence salts, including the long known [AgI]+[AgIII(CF3)4]− (Ag-1), has been synthesized from AgF and CF3SiMe3 upon open flask conditions, and fully characterized. The...

chemistry-europe.onlinelibrary.wiley.com
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September is there with the start of a new academic year... A good time to have a look back on 2022-2023, and highlight the work of talented PhD students and Post-Doctoral fellows ! Congratulation to @Julien_Petit08 doi.org/10.1002/chem.2022039…

Taming the Lewis Superacid Al(ORF)3 (RF=C(CF3)3): DFT Guided Identification of the “Stable yet...

A predictive DFT study of L→Al(ORF)3 (L=Lewis bases) adducts allowed the identification of (iPr2S)→Al(ORF)3 as a “stable yet reactive” adduct, able to act as a masked Lewis superacid. It provides a...

chemistry-europe.onlinelibrary.wiley.com
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September is there with the start of a new academic year... A good time to have a look back on 2022-2023, and highlight the work of talented PhD students and Post-Doctoral fellows ! Congratulation to @SBennaamane and B Rialland doi.org/10.1002/anie.2022091… doi.org/10.1002/chem.2022037…
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Our latest update on ammonia synthesis at atmospheric pressure using boron radicals : doi.org/10.1002/anie.2022091… Congratulations to Soukaina, Barbara and Lhoussain !
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A post-doctoral position is available in our team on dinitrogen activation !
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📢Big congratulations to the COP Team led by @samilakhdar1 for the great @ScienceMagazine article on XAT reactivity enabled by hydrogen tunneling. Awesome collaboration with @LeonoriLab. Well done guys!!!👏 @INC_CNRS @CNRS_Toulouse @UT3PaulSabatier @CNRS science.org/doi/10.1126/scie…

Halogen-atom and group transfer reactivity enabled by hydrogen tunneling

Cyclohexadiene derivatives deliver hydrogen atom equivalents through a tunneling mechanism.

science.org
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Our latest update about electrochemical reductive dinitrogen splitting : doi.org/10.1002/anie.2022098…

Molecular Electrochemical Reductive Splitting of Dinitrogen with a Molybdenum Complex **

N2 splitting is achieved with a simple Mo complex at a carbon electrode. Controlled reduction (a 3 electron transfer process) at −1.4 V (vs. SCE) and ambient conditions (room T and atmospheric P)...

onlinelibrary.wiley.com
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Congratulations to @Julien_Petit08 who was awarded the 2021 thesis prize from the Coordination Chemistry Division of the French Chemical Society ! new.societechimiquedefrance.…

Prix de thèse 2021 - Société Chimique de France (SCF)

Le prix de thèse DCC 2021 a été attribué conjointement à : Julien Petit pour ses travaux portant sur l’« Exploration d’une nouvelle réactivité en

new.societechimiquedefrance.fr
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Congratulations to @Julien_Petit08 for this very nice work on challenging in-situ generated cationic nickel complexes for ethylene oligomerization pubs.acs.org/doi/10.1021/acs…

Synthesis of L2Ni(ORF)2 (RF = C(CF3)3) Complexes and Their Reactivity in Ethylene Oligomerization

Abstract. A family of L2Ni­(ORF)2 (L2: (Cy3PO)24, dcpmS 5, dppf 9, bipyMe210; RF = C­(CF3)3) complexes is synthesized via selective substitution of 2 equiv

pubs.acs.org
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Many thanks to Julien for his very nice achievement, and to @GrimaudLaurence , Chloé Thieuleux, Marc Visseaux and @vinc_cesar for having evaluated Julien's work. Such a nice day...
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Do you want to learn more about alkene oligomerization via metallacycles ? Just have a look to the insightful review from Julien, Lionel and Nicolas. sciencedirect.com/science/ar… Special link to free access (within the next 40 days) authors.elsevier.com/c/1dtJt… @Julien_Petit08 @LHFA_CNRS
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Are you passionate about Sustainable Polymers and the Environment🌍? Are you looking for a unique PhD opportunity? Join our teams @csctbath @PlymouthMarine to work on an exciting project across Chemistry and Marine Ecology with @LindequePk and @SciMatty⬇️ findaphd.com/phds/project/ne…

NERC GW4+ DTP PhD project - Polymers from sugars: development of emerging sustainable plastics and...

PhD Project - NERC GW4+ DTP PhD project - Polymers from sugars: development of emerging sustainable plastics and investigation of their impact on the marine environment at University of Bath, listed...

findaphd.com
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Hello everyone, I'm looking for a new position as researcher in organic chemistry around the Burgundy or Rhône-Alpes areas. I'm interested by all opportunities (public or companies) I'm available immediately! Thank you to share this post. #chemistry #chemjob
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We're looking for innovative post-doctoral researchers to join us at @iCASTinfo @csctbath, within @UniofBath. Several positions are available, including in the area of sustainable polymers. Get in touch and apply! Deadline: 21 October 2021. bath.ac.uk/jobs/Vacancy.aspx…
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We are hiring ! Interested in organometallic chemistry at the service of biomimicry ? Join us to develop sythetic nitrogenase cofactor mimics for the reduction of CO2 ! Read more about this Post-Doctoral position here : bit.ly/3DSJry4 @LHFA_CNRS
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Congratulation to @LucaJDemonti for his work on the quantitative preparation of Ag(III) complexes and their use in cross coupling reaction ! @LHFA_CNRS @NebraNoel doi.org/10.1002/chem.2021028…

Cross‐Coupling through Ag(I)/Ag(III) Redox Manifold

Teaching silver to do the trick. Most crucial steps towards oxidative trifluoromethylation via AgI/AgIII redox shuttles are herein deciphered. This innovative cross-coupling, analogous to the CEL...

chemistry-europe.onlinelibrary.wiley.com
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Congratulation to Julien @Julien_Petit08 and Anthony Cavaillé for this nice paper on double alpha,alpha-CH insertion using iron ! @LHFA_CNRS doi.org/10.1039/D1DT00610J
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Congratulation to @SBennaamane, Maria, Andrea and Theo for this very nice piece of work, giving a rare example of catalytic reduction of dinitrogen in soft conditions @LHFA_CNRS doi.org/10.1002/anie.2021060…
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