@SupRaLabRome

Lab of SUPramolecular chemistry, RAdical reactivity & catalysis at @SapienzaRoma. Joining groups & forces from @S__DI_STEFANO @olivo_giorgio @lanzalunga

 Rome, Italy
sites.google.com/a/uniroma1.it/stefanodistefano-eng/
Joined November 2021
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23Media
Deciphering the Role of Crown-ether Receptor Orientation in C-H Oxidation Catalyzed by Supramolecular Nonheme FeIV(O) Complexes (Stefano Di Stefano @S DI_STEFANO, Giorgio Olivo @olivo_giorgio and co-workers @SupRaLabRome) • onlinelibrary.wiley.com/doi/…

Deciphering the Role of Crown‐ether Receptor Orientation in C‐H Oxidation Catalyzed by Supramolec...

Understanding how modification of receptor position and orientation in a supramolecular catalyst affects its efficiency is key for rational catalyst design but still underexplored. Herein, we...

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#ChemSystemsChem Coacervate-Droplet Cased Synthetic Cells Regulated By Activated Carboxylic Acids (ACAs) (Job Boekhoven and co-workers) @BoekhovenLab @ValMatteo_ @SupRaLabRome #openaccess 🔓 onlinelibrary.wiley.com/doi/…
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I'm super happy to see online our latest paper in collaboration with @BoekhovenLab! We coupled peptide-based coacervates formation with the ACA reaction cycle - offering a new versatile approach toward synthetic life. @S__DI_STEFANO @SupRaLabRome chemistry-europe.onlinelibra…

Coacervate‐Droplet Cased Synthetic Cells Regulated By Activated Carboxylic Acids (ACAs)

The activated carboxylic acid (ACA) reaction cycle, usually employed to transiently change the solution pH, has been exploited to precisely control the lifetime of peptide-based coacervates. This...

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Time, stand still… it feels like a dream 🥹 Our work has been published in @ScienceMagazine!!! 🚀✨ A new chiral catalyst to perform hydrogen atom abstraction in an enantioselective manner. Hope you enjoy the read! science.org/doi/10.1126/scie…

A chiral hydrogen atom abstraction catalyst for the enantioselective epimerization of meso-diols

Hydrogen atom abstraction is an important elementary chemical process but is very difficult to carry out enantioselectively. We have developed catalysts, readily derived from the Cinchona alkaloid...

science.org
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SupRa lab Rome retweeted
Jake Greenfield@JakeyLG27 Sep 2024
🚨You know what Imine? Our systematic structure-property relationship study on imine photoswitches is now out in @angew_chem 💡🚥🚀We explored condensed phase switching and captured a Z-arylimine💎structure! Feat. @GalliumWu + LasseK @Uni_WUE #AIPs doi.org/10.1002/anie.2024154…
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Truly honored to receive this award from @RSEQUIMICA and @RSEF_ESP! This belongs to all the brave students and postdocs who have trusted me from day one, and also to those who supported me as a postdoc and group leader in their time. Your support means everything. Thank you! 🙏
ICIQ@ICIQchem30 Jul 2024
#ICIQNews 🏅Dr. @JA_Berrocal awarded with the "Joven Investigador en Polímeros" recognition from the @RSEQUIMICA and @RSEF_ESP 🏆This award highlights the excellence of young researchers from the Group of Polymers (#GEP) Read more 🔗 iciq.org/dr-jose-a-berrocal-…
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SupRa lab Rome retweeted
ChemCatChem@ChemCatChem18 Jun 2024
Homogeneous Iron Catalyzed C-H Amination (Giorgio Olivo and co-workers) @olivo_giorgio @SupRaLabRome @PossentiDario onlinelibrary.wiley.com/doi/…

Homogeneous Iron Catalyzed C−H Amination

Homogeneous iron catalysts are emerging as an attractive and sustainable method for the amination of C(sp3)−H bonds and aromatic rings, mainly via high-valent iron-nitrene intermediates. This review...

chemistry-europe.onlinelibrary.wiley.com
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Out now in @ChemCatChem: a review on Fe-catalyzed C-H amination by @olivo_giorgio and me. We summarize recent advances in catalysis, mechanisms, and isolated intermediates. Thanks to my supervisor @olivo_giorgio and to all @SupRaLabRome for their support! chemistry-europe.onlinelibra…

Homogeneous Iron Catalyzed C−H Amination

Homogeneous iron catalysts are emerging as an attractive and sustainable method for the amination of C(sp3)−H bonds and aromatic rings, mainly via high-valent iron-nitrene intermediates. This review...

chemistry-europe.onlinelibrary.wiley.com
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Only 11 days left to apply for a PhD position in our group @ICIQ! 🌟 You will learn how to be an organic chemist, a polymer chemist, and a material scientist all at once. And if this is not enough, we are not far from the beach at all 🌊🧪
ICIQ@ICIQchem12 Jun 2024
#ICIQJobs 🚀 Ready to take your chemistry career to the next level? 🔬 Conduct research with world-class Group Leaders 🌍 Opportunities for international collaborations 💡 Develop both technical and soft skills Apply now🔗careers.iciq.org/jobs/450134… @RSEQUIMICA @quimics
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👇 Check out our paper on how the effect of the solvent affects the activated carboxylic acids (ACAs) reaction cycle coupled to a DL of imines. I hope it will be helpful to everyone using this chemistry!! Congratulations to the team 💪🏻@S__DI_STEFANO @gianfry_il_prof @SupRaLabRome
ChemEurJ: Chemistry - A European Journal@ChemEurJ23 May 2024
Kinetic Trapping of an Out-of-Equilibrium Dynamic Library of Imines by Changing Solvent (Stefano Di Stefano and co-workers) @S_DI_STEFANO @gianfry_il_prof @ValMatteo_ @SupRaLabRome onlinelibrary.wiley.com/doi/…

Kinetic Trapping of an Out‐of‐Equilibrium Dynamic Library of Imines by Changing Solvent

When an Activated Carboxylic Acid (ACA) is employed to perturb a dynamic library of imines, the nature of the solvent has a crucial role in defining the non-equilibrium state of such library. A...

chemistry-europe.onlinelibrary.wiley.com
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Kinetic Trapping of an Out-of-Equilibrium Dynamic Library of Imines by Changing Solvent (Stefano Di Stefano and co-workers) @S_DI_STEFANO @gianfry_il_prof @ValMatteo_ @SupRaLabRome onlinelibrary.wiley.com/doi/…

Kinetic Trapping of an Out‐of‐Equilibrium Dynamic Library of Imines by Changing Solvent

When an Activated Carboxylic Acid (ACA) is employed to perturb a dynamic library of imines, the nature of the solvent has a crucial role in defining the non-equilibrium state of such library. A...

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Hot off the press! Our work on the modulation of Fe(IV)=O reactivity via supramolecular recognition has been just published on @angew_chem ! Congrats to all authors @SupRaLabRome @QBIScat_UdG @FedeFrateloreto @S__DI_STEFANO @MiquelCostas @Ale_Fagnano onlinelibrary.wiley.com/doi/…

Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation

We report evidence that supramolecular substrate binding increases several aspects of iron (IV) oxo (Fe(IV)=O) reactivity not only in nonheme oxygenases but also in synthetic models. Recognition-in...

onlinelibrary.wiley.com
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Super happy to see my first cover art out now on @ChemEurJ!! If you missed it: doi.org/10.1002/chem.2023038… @SupRaLabRome

Signal Transduction Allows Temporal Control of the Potential of a Concentration Cell Driven by the...

Time-controlled pH variations enabled by the decarboxylation of nitroacetic acid are transduced into time-controlled voltage variations. Such variations are exploited to govern the operation of...

chemistry-europe.onlinelibrary.wiley.com
ChemEurJ: Chemistry - A European Journal@ChemEurJ23 Feb 2024
#OnTheCover Signal Transduction Allows Temporal Control of the Potential of a Concentration Cell Driven by the Decarboxylation of an Activated Carboxylic Acid onlinelibrary.wiley.com/doi/… onlinelibrary.wiley.com/doi/…
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Signal Transduction Allows Temporal Control of the Potential of a Concentration Cell Driven by the Decarboxylation of an Activated Carboxylic Acid (Stefano Di Stefano and co-workers) @S_DI_STEFANO @GiorgioCapocasa @FedeFrateloreto @ValMatteo_ @SupRaLabRome onlinelibrary.wiley.com/doi/…

Signal Transduction Allows Temporal Control of the Potential of a Concentration Cell Driven by the...

Time-controlled pH variations enabled by the decarboxylation of nitroacetic acid are transduced into time-controlled voltage variations. Such variations are exploited to govern the operation of...

chemistry-europe.onlinelibrary.wiley.com
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Our latest work, done in collaboration with @MassimoBietti (@unitorvergata), on selective aliphatic C-H oxygenation enabled by polarity enhancement is now available in @J_A_C_S. Congratulations Sergio, @MarcoGale94 and all the authors! @MiquelCostas pubs.acs.org/doi/10.1021/jac…

Highly Selective C(sp3)–H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhance...

Abstract. A detailed study on the C­(sp3)–H bond oxygenation reactions with H2O2 catalyzed by the [Mn­(OTf)2(TIPSmcp)] complex at methylenic sites of cyclo

pubs.acs.org
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SupRa lab Rome retweeted
xribas@ribas_xavi22 Sep 2023
Don’t miss the opportunity, still a few days left! A PhD position (FPI, four years) in Supramolecular Chemistry is open in my group at @QBIScat_UdG starting Jan 2024. Please send asap your applications (deadline 30 Set 2023) @IQCCUdG @univgirona 👇👇
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SupRa lab Rome retweeted
J. Am. Chem. Soc.@J_A_C_S5 Aug 2023
Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ-C–H Bonds | JACS @IQCCUdG @univgirona @palone_andrea @ArnauCall @MiquelCostas @MassimoBietti @unitorvergata #Enantioselective #Catalysis #CHFunctionalization #Lactone pubs.acs.org/doi/10.1021/jac…

Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ‑C–H Bonds

Abstract. Chiral oxygenated aliphatic moieties are recurrent in biological and pharmaceutically relevant molecules and constitute one of the most versatile

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We are very happy to announce the 2024 Girona Seminar (29-31 May 2024), which will focus on supramolecular chemistry. We have a fantastic line-up of speakers confirmed and a wonderful venue in our beautiful city! Please check gironaseminar.org for details @IQCCUdG

Home

gironaseminar.org
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ISNSC 2024@ISNSC20241 Jun 2023
Next speaker is @GabriMelchi99 explaining us Dissipative Dynamic Covalent Chemistry Based on The Transamination Reaction #SupraChemDays2023
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A new doctor is on the road! 😎 @SupRaLabRome @S__DI_STEFANO – at Rome, Lazio
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