what is life, but a figment of our imagination. Chemistry graduate student in the @mindiolagroup.

El Paso, TX
Joined October 2010
I’m happy to share two recent papers on our ketenyl anion chemistry: In @J_A_C_S, we report the isolation of the long-elusive pyridylketenyl🔥 anion, an ideal precursor for N-fused heterocycles. Congrats to Stephan for taming this challenging species. pubs.acs.org/doi/10.1021/jac…
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🌻The “God of #Fluorine,” Karl Otto Christe, passed away on April 19, 2026, in California. He was born in Ulm, Germany, and studied chemistry at the University of Stuttgart @Uni_Stuttgart from 1957 onwards. He received his PhD in 1961 for work with Josef Goubeau and emigrated to California a year later. There he worked first for #Stauffer Chemical Co. and from 1967–1994 for Rockwell International, a company well known for producing rocket fuels. From 1994–2005, Christe was a Senior Staff Advisor at the Air Force Research Laboratory of Edwards Air Force Base @AFResearchLab, and in parallel he was a Professor at the Loker Hydrocarbon Research Institute of the University of Southern California @UniversityofSo5. Christe was most famous for the first completely chemical synthesis of elemental fluorine. Furthermore, he synthesized iconic ions like NF₄⁺ and ClF₆⁺ as well as extremely reactive polynitrogen ions like the linear-angled N₅⁺ and the cyclic N₅⁻, and he was well known as an expert in #EnergeticMaterials. He received the “Apollo Achievement Award” for his contributions to the Apollo missions and a wide range of prizes from the ACS @AmerChemSociety, the #SFC, and the GDCh @GDCh_aktuell. Christe’s contributions to inorganic chemistry cannot be overestimated.
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Casey smacked the Schmitt out of this one 😤
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Matt retweeted
Mechanistic Insights into H–H Bond Cleavage and [1 + 2] Cycloaddition of Ethylene Mediated by Triplet Pnictinidenes | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Zhang and Su @InorgChem #pnictinidenes #triplet #HHcleavage #1plus2CA #ethylene #DFT #ASM #distortion_interaction
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Nickel foam unlocks chemoselective nitroarene reduction under mild reaction conditions in the presence of sensitive functional groups. J. Am. Chem. Soc. 2026, DOI: 10.1021/jacs.5c19584 lnkd.in/eFiVXFax @ACSPublications @J_A_C_S @queensu @queensuResearch
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SuzukiMe: A Tactically Mild Methylation Reagent ( @ChemRxiv ) : chemrxiv.org/doi/full/10.264….
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N–H/P–H bond activation of ammonia, amines and phosphines at a transient borylene (@LabBraunschweig): pubs.rsc.org/en/content/arti… (@ChemicalScience).
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The long-standing challenge of converting alkenes directly to alkynes—classically a harsh two-step halogenation/elimination—is solved by Ning Jiao & team! 🔗nature.com/articles/s41586-0… #OrganicChemistry #OrganicSynthesis #Alkyne #Nature #Chemistry
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Group 13 Metals as L-type Ligands for Transition Metals for Structure and Bonding (@martinez_a_j, @arxiv): arxiv.org/abs/2511.03513 (@SpringerNature, @CamposGroup, @hellen_videa, @geqo_rseq, @CIQSO_UHU).
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Zwitterionic Phosphorus(I) Compounds Supported by a Bis(carbene)borate: Synthesis, Protonation, and Thermodynamics of P–H Bonds (@InorgChem): pubs.acs.org/doi/10.1021/acs….
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Matt retweeted
Controlling Redox and Photophysical Properties of First-Row Transition Metal Complexes via Ligand Perhalogenation | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Sellin, Wenger, Malischewski, and co-workers @InorgChem #nickel #perhalogenation #isocyanide #MLCT #DFT
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MOLECULAR ZINTL PHASES with tetra-anionic Si, Ge, Sn, Pb accessible using soluble Mg(0). Although all E(4-) anions are full valence-shell octets, they are highly reactive. The Sn(-IV) complex is an 8e-reductant @FAU shorturl.at/InmD6 @NatureSynthesis
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The true size of Portugal compared to Spain
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Toguchi, Hamawaki, and Prof. Sakakibara's work is available in @ChemRxiv A Modular Strategy for the Gram-Scale Synthesis of Tetraarylammonium Salts chemrxiv.org/doi/full/10.264…
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