@pengwanglab

Synthetic organic chemistry lab @ SIOC, metal catalysis, main group chemistry, asymmetric catalysis.

 Shanghai
wang-labs.org/
Joined March 2014
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One representative example of asymmetric catalysis enabled by spirosilacycle-based ligands. Using the newly developed SPSiOP, we have realized enantioselective hydrosilylation of diverse allenes via nickel catalysis. Just out @angew_chem Check out: onlinelibrary.wiley.com/doi/…
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CCS Chemistry
@CCSChemistryJul 31
Switchable Regiodivergent Hydrogenation of Naphthol and Naphthylamine Derivatives via a Combination of Homogeneous and Heterogeneous Catalysis chinesechemsoc.org/doi/10.31… #chemistry #openaccess #science #chemtwitter
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Nickel‐Catalyzed 1,2‐Arylalkenylation of Unactivated Alkenes Enabled by a Native Hydroxy Group - Wang - Angewandte Chemie International Edition - Wiley Online Library onlinelibrary.wiley.com/doi/…
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Yulab@YulabJinJun 3
Unlike functional group conversion, C-H bonds too far or too close are both hard to activate, but it is also the beauty if we can. Piperidine as the top pharmacophore, needs reaction to edit, but C-3 is too close, one bond extension works: Nat. Catal: rdcu.be/fl2xC.
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J. Am. Chem. Soc.@J_A_C_SMay 13
Nickel-Catalyzed Regioselective Dihydrosilylation of Allenes | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Nickel-Catalyzed Regioselective Dihydrosilylation of Allenes

Abstract. Herein, we report a nickel-catalyzed regioselective dihydrosilylation of allenes to access 1,3-bis­(silane)­s bearing two remote silyl groups. En

pubs.acs.org
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J. Am. Chem. Soc.@J_A_C_SMay 16
Nickel-Catalyzed Remote Substitution of Alcohols | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Nickel-Catalyzed Remote Substitution of Alcohols

Abstract. Here, we report a nickel-catalyzed remote substitution of unprotected alkenyl alcohols with arylboronic acids, enabling C–C bond formation at pos

pubs.acs.org
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With a bulky 1,3-diketone ligand, a nickel-catalyzed remote substitution of unprotected alkenyl alcohols with arylboronic acids has been realized, enabling distal C–C bond formation directly from native alcohols. Just out @J_A_C_S | pubs.acs.org/doi/full/10.102…
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Check out our latest publication @J_A_C_S . A nickel-catalyzed regioselective dihydrosilylation of allenes has been realized, accessing 1,3-bis(silane)s bearing two remote silyl groups in high regioselectivity. Congrats to Qing-Yan. pubs.acs.org/doi/10.1021/jac…
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Check out our latest publication @J_A_C_S . Using the SPSiP ligand, we report the first example of enantioselective Pd-catalyzed intramolecular alkynylamination of alkenes at room temperature. pubs.acs.org/doi/10.1021/jac…
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J. Am. Chem. Soc.@J_A_C_S8 Oct 2025
Photoredox/Ni-Catalytic Synthesis of cis-Vinyl Iodides from Acetylene | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Photoredox/Ni-Catalytic Synthesis of cis-Vinyl Iodides from Acetylene

Abstract. The stereoselective synthesis of cis-vinyl iodides represents a long-standing challenge in organic synthesis, with Stork–Zhao olefination remaini

pubs.acs.org
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Wang Lab@SIOC retweeted
The Nobel Prize
@NobelPrize8 Oct 2025
“My parents could barely read or write. It’s been quite a journey, science allows you to do it.” New laureate Omar Yaghi was in the middle of changing flights when we reached him, just after he heard that he had been awarded the 2025 #NobelPrize in Chemistry. In this interview we speak about his early life as a refugee in Jordan and the overwhelming draw of the beauty of chemistry: “I set out to build beautiful things and solve intellectual problems.” Listen now:
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Three scientists win Nobel Prize in chemistry for the development of metal-organic frameworks phys.org/news/2025-10-scient…

Three scientists win Nobel Prize in chemistry for the development of metal-organic frameworks

Three scientists won the Nobel Prize in chemistry Wednesday for their development of new molecular structures that can trap vast quantities of gas inside, laying the groundwork to potentially suck...

phys.org
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Just out @ChemicalScience One more example of Migratory 1,n-Cycloannulation Reaction (MCAR) of alkenes for modular and diverse synthesis of oxaheterocycles. Check out: pubs.rsc.org/en/content/arti…
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We have realized the modular and diverse synthesis of oxaheterocycles via Pd-catalyzed migratory 1,n-cycloannulation of alkenes. Check out our recent preprint @ChemRxiv go.shr.lc/422uwz1
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Prof. Jin-Quan Yu (@YulabJin) will receive the 5th Akira Suzuki Award for his research on C–H bond activation, which makes it easier to build complex molecules. His work accelerates advances in pharmaceuticals, molecular tools and materials science. More: ow.ly/z0BL50WhOQf

Jin-Quan Yu selected for the 5th Akira Suzuki Award - Scripps Research Magazine

Jin-Quan Yu, the Bristol Myers Squibb Endowed Chair in Chemistry and the Frank and Bertha Hupp Professor in Chemistry at Scripps Research, has been selected as the recipient of the 5th Akira Suzuki...

magazine.scripps.edu
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Finally out @ChemicalScience We have realized a Rh-Catalyzed Enantioselective Hydrosilylation of Unactivated Alkenes. Congrats to Yichen, Hao-Yang and Heng. Check out here: pubs.rsc.org/en/content/arti…
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This work was previously deposited @ChemRxiv on October 4, 2024. Available at: go.shr.lc/40pEF8Z

Rh-Catalyzed Enantioselective Hydrosilylation of Unactivated Alkenes | ChemRxiv

Here, we report a highly efficient rhodium-catalyzed enantioselective hydrosilylation of unactivated alkenes, achieving excellent regioselectivity and high enantioselectivity. The use of a commerci...

chemrxiv.org
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Wang Lab@SIOC retweeted
J. Am. Chem. Soc.@J_A_C_S1 May 2025
Cu-Catalyzed Enantioselective Carbene Insertion into Ge–H and Si–H Bonds Enabled by SPSiBox with a Tunable Chiral Pocket | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Cu-Catalyzed Enantioselective Carbene Insertion into Ge–H and Si–H Bonds Enabled by SPSiBox with a...

Abstract. Here, we report the Cu-catalyzed asymmetric carbene insertion into both Ge–H and Si–H bonds with α-trifluoromethyl diazo compounds, enabled by a

pubs.acs.org
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Congratulations to Alex! He has prepared a nice review on the catalytic atroposelective construction of diaryl ethers and diaryl amines. Just out @ACSCatalysis | pubs.acs.org/doi/10.1021/acs…
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Finally out in JACS. Congrats to Shi-Hao and Sheng-Ye. We have developed an SPSiOL-based bisoxazoline ligand (SPSiBox), featuring a tunable chiral pocket. Plz check out here: pubs.acs.org/doi/full/10.102…
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