Molecular Inorganic Chemistry and Catalysis Group @unibielefeld 📌Open-Shell Main-Group and Organometallic Chemistry enthusiastic C-Donors📌
Bielefeld, Deutschland
Joined February 2018
- Tweets917
- Following774
- Followers2.8K
- Likes4.2K
Pinned Tweet
Annulated 1,4-Disilabenzene-1,4-diide and Dihydrogen Splitting @J_A_C_S kudos @Falk_Eb @Ghadwal_Group @unibielefeld @aromaticity_eu pubs.acs.org/doi/10.1021/jac… #silicon #aromaticity #hydrogen #main_group thanks @dfg_public
Ghadwal Group retweeted
QUESTION TO THE COMMUNITY: Since COVID it is very difficult to get GOOD (STRONG) glovebox gloves. And they are very expensive! Any tips where to get normally priced good gloves? You can also direct-mail me. Thanks for your advice!
Ghadwal Group retweeted
Have a look our recent article on Nickel-Catalyzed Dehydrogenative Zn–Zn Coupling to a Zn(I) Dimer and Its Reactivity - now published in Chemical Communications pubs.rsc.org/en/content/arti… Congratulations to Sagrika💐
@ANRFIndia @niser_official @ChemCommun
Ghadwal Group retweeted
@Ghadwal_Group demonstrate the impact of C2-terphenyl substitution patterns (p-terphenyl vs. m-terphenyl) on the redox behavior and stability of radicals and anions derived from N-heterocyclic carbenes #NHC #openaccess 🔓 onlinelibrary.wiley.com/doi/…
Ghadwal Group retweeted
Our work on the reaction of an NHC with carbon suboxide is out in Chemical Science.
Thanks to PhD grad Tanner George for his persistence and attention to detail on this project, collaborator Erin Johnson (Dalhousie), and @NSERC_CRSNG for funding.
pubs.rsc.org/en/content/arti…
Our latest contribution to #OpenShell chemistry from @Ghadwal_Group — Terphenyl Radicals and Anions: Tuning Stability and Redox Properties via Substituent Patterning — now published in @angew_chem!
Thanks to @dfg_public for the support!
onlinelibrary.wiley.com/doi/…
ALT https://onlinelibrary.wiley.com/doi/10.1002/anie.202520260
Ghadwal Group retweeted
#CoverFeature Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4-diides: Interplay Between Diradical Character & Aromaticity (Israel Fernández and co-workers) ChemEurJ 45/2025 doi.org/10.1002/chem.2025019… • onlinelibrary.wiley.com/doi/…
Ghadwal Group retweeted
Nice cover designed by @DanielPinardo to illustrate our work in @ChemEurJ on Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4‐diides: Interplay Between Diradical Character and Aromaticity @Ghadwal_Group
chemistry-europe.onlinelibra…
Absolutely beautiful cover by Dani and Isra! @isra_group chemistry-europe.onlinelibra… @ChemEurope
Thanks for having me on board - @Ghadwal_Group
Ghadwal Group retweeted
Cool germanium BCB- and it’s a nonclassical diradical ⚡️⚡️⚡️ Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid - Ebeler - Angewandte Chemie International Edition - Wiley Online Library onlinelibrary.wiley.com/doi/…
In case you are interested in the German version: onlinelibrary.wiley.com/doi/…
@Ghadwal_Group
Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/… #maingroup #diradicals thanks to @dfg_public
Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/… #maingroup #diradicals thanks to @dfg_public
Ghadwal Group retweeted
Benzene, PAHs, macrocycles, nanorings, etc.
We thought we understood aromaticity.
BDF challenges what we see, what we measure, and what we believe about delocalized bonding. | ChemRxiv - go.shr.lc/3IFFvb5
Ghadwal Group retweeted
Check out our work just accepted in @ChemEurJ on Understanding Small Molecule Activation by Heavier Benzene 1,4‐diides: Interplay between Diradical Character and Aromaticity @DanielPinardo @Ghadwal_Group @UCM_OrgChem chemistry-europe.onlinelibra…
Ghadwal Group retweeted
Cyclic pnictogen-radical cations, valence-isoelectronic to the elusive aryl radical anions of Birch reductions, have been successfully isolated as crystalline solids showcasing reversible single-electron-transfer (SET) @Ghadwal_Group #openaccess 🔓 onlinelibrary.wiley.com/doi/…
Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions—just published in @angew_chem Congratulations to Henric and all @Ghadwal_Group @bruin_bas Thanks @dfg_public
onlinelibrary.wiley.com/doi/…
ALT Annulated Radical Cations with a C4E2-Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions
Paneth’s mirrors and the isolation of methyl radicals: chemistryworld.com/opinion/p…
Ghadwal Group retweeted
Lithium Anionic Dicarbenes or Acetylides: What is in the Name? (Rajendra S. Ghadwal and co-workers) @Ghadwal_Group #AngewandteVIP #openaccess 🔓 onlinelibrary.wiley.com/doi/…
Here is the German version, in case:
onlinelibrary.wiley.com/doi/…
The final proofed version is now online and has earned VIP status. Thanks to the reviewers for ranking this work #outstanding— top 5%! and providing constructive feedback. Thanks @angew_chem and @dfg_public
@Ghadwal_Group @ArneMrsl
The final proofed version is now online and has earned VIP status. Thanks to the reviewers for ranking this work #outstanding— top 5%! and providing constructive feedback. Thanks @angew_chem and @dfg_public
@Ghadwal_Group @ArneMrsl
Lithium Anionic Dicarbenes or Acetylides: What is in the Name? (Rajendra S. Ghadwal and co-workers) @Ghadwal_Group #AngewandteVIP #openaccess 🔓 onlinelibrary.wiley.com/doi/…
Congratulations 🙌 and all the best for you and your future plans 💪💪💪
Huge thanks to my mentors Prof Nagendran @SNagendranGroup, Prof Ghadwal @Ghadwal_Group, and Prof Schulz @unidue for their continuous support and guidance throughout this journey. I also would like to thank all my collaboraters for their support.