@bruin_bas

Chemistry professor (UvA Amsterdam). Research interests: Organometallic Chemistry & Catalysis, Radicals, Carbenes, Nitrenes

homkat.nl/basdebruin/
Joined December 2013
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Delighted to share our recent work published in @J_A_C_S!! In this study, we use pyrido-oxazolone for the very first time as a nitrene surrogate, enabling a photoinduced N–N coupling reaction. Fantastic collaboration with @bruin_bas @ChattopadhyayL1 pubs.acs.org/doi/10.1021/jac…

Photo-Induced Intermolecular N–N Cross-Coupling via Nitrene Transfer Reaction

Abstract. An intermolecular N–N cross-coupling reaction induced by light was established under metal-free conditions. In addition, this work showed that py

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Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolecular C(sp3)–H Amination of Aliphatic Azides | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Selective Chiral Diamine-bisoxazoline Iron(II) Catalysts for Pyrrolidine Formation via Intramolec...

Abstract. The utilization of iron-catalyzed intramolecular C­(sp3)–H amination starting from organic aliphatic azides, which are easily available precursor

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Advancing Light-Triggered Alkyd Paint Curing: (Cp)FeII(naphthalene)](PF6) Catalysts with Enhanced Photosensitivity and Increased Performance in Pigmented Alkyd Paints by Bas de Bruin and co-workers (@bruin_bas, @UvA_Amsterdam) #OpenAccess 🔓 onlinelibrary.wiley.com/doi/…

Advancing Light‐Triggered Alkyd Paint Curing: (Cp)FeII(naphthalene)](PF6) Catalysts with Enhanced...

[(Cp)FeII(naphthalene)](PF6) catalysts are reported with improved curing efficiency of alkyd paints compared to [(Cp)FeII(arene)](PF6), particularly in dark-pigmented formulations. Their improved...

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Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions—just published in @angew_chem Congratulations to Henric and all @Ghadwal_Group @bruin_bas Thanks @dfg_public onlinelibrary.wiley.com/doi/…
Annulated Radical Cations with a C4E2-Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions

ALT Annulated Radical Cations with a C4E2-Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions

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Geweldig nieuws: hoogleraar Gert-Jan Gruter @HimsUva en @Avantium is benoemd tot Ridder in de Orde van de Nederlandse Leeuw voor zijn buitengewone bijdragen aan duurzame chemie en zijn inzet voor innovatie en maatschappelijke impact. Van harte @GJGruter 🎊 go.uva.nl/3BSXE1v

Koninklijke onderscheiding voor Gert-Jan Gruter

Prof. dr. Gert-Jan Gruter, bijzonder hoogleraar Industrial Sustainable Chemistry aan de Universiteit van Amsterdam, is op 22 oktober 2024 benoemd tot Ridder in de Orde van de Nederlandse Leeuw....

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At last night's Ig Nobel prize ceremony, teams from the UvA took home not one, but TWO prizes 🎉. Read below how drunken worms 🪱🍸and more coin tosses 💰than seems strictly necessary brought the prizes back to the Netherlands. go.uva.nl/3XGCpbB

UvA scoops two Ig Nobel prizes

What do intoxicated worms and more than a third of a million coin tosses have in common? They’ve both landed the UvA among the recipients of this year’s Ig Nobel prizes. The Ig Nobels have been...

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Sander Woutersen, Daniel Bonn, Tess Heeremans and Antoine Deblais, @HimsUva, @IoP_UvA @UvA_Science received the Ig Nobel Prize for chromatography of sober and druk worms: linkedin.com/posts/van-t-hof…

#ignobel | Van 't Hoff Institute for Molecular Sciences (University of Amsterdam) | 16 comments

Enjoy this clip from yesterday's #IgNobel award ceremony where Sander Woutersen, Tess Heeremans, Antoine Deblais and Daniel Bonn received the Chemistry Prize and re-enacted their experiment using...

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Congratulations Henric @HenricSteffen & Dennis @Dennis_Rott on your recent work @Ghadwal_Group on "Non‐Kekulé m‐Quinodimethane Singlet Diradicals" another fruitful collaboration (thanks Bas) with @bruin_bas @UvA_Amsterdam - @dfg_public @AvHStiftung 👉 chemistry-europe.onlinelibra…
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Trots op mijn grote kleine meid, omdat ze haar HBO diploma heeft gehaald
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De moeite van het lezen meer dan waard #UvA #protest folia.nl/nl/opinie/162218/ha…

Han van der Maas | De zwakte van het moderne activisme

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Didam op stelten 2024
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Check out this interesting approach to generate cobalt carbene radical complexes by our talented PhD student @DemiSnabilie xitter.cf/DemiSnabilie/status/17…
Demi D. Snabilié@DemiSnabilie29 May 2024
Happy to share that my first research article of my PhD is now published in @Orgmet_ACS.🥳🧪 We generated a cobalt #carbene radical complex from dimethyl malonate as starting reagent. How? ➡️ Check out: pubs.acs.org/doi/10.1021/acs… #chemtwitter @ARCCBBC

Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor

Abstract. Radical-type carbene transfer catalysis is an efficient method for the direct functionalization of C–H and CC bonds. However, carbene

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Happy to share that my first research article of my PhD is now published in @Orgmet_ACS.🥳🧪 We generated a cobalt #carbene radical complex from dimethyl malonate as starting reagent. How? ➡️ Check out: pubs.acs.org/doi/10.1021/acs… #chemtwitter @ARCCBBC

Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor

Abstract. Radical-type carbene transfer catalysis is an efficient method for the direct functionalization of C–H and CC bonds. However, carbene

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Check out in @NatureComms our new paper on the photocatalytic C(sp2)–C(sp3) Suzuki−Miyaura cross-coupling of aryl bromides with alkyl boranes: nature.com/articles/s41467-0… Great work by @_lucapaldo, @Ting__Wan, Jonas, Angela, @FelixJdeZwart, @bruin_bas and @tnoel82 #FlowChemistry
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Bas de Bruin retweeted
ARC CBBC@ARCCBBC4 Apr 2024
#ThrowbackThursday! In '2022 at a glance', we placed Marie Brands (@UvA_Amsterdam) in the spotlights! Read more about her research on page 12 of '2022 at a glance': arc-cbbc.nl/uploads/2022-at-… @MarieBrands
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Gas Evolution as a Tool to Study Reaction Kinetics Under Biomimetic Conditions (Joost N. H. Reek and co-workers) @ej_meeus @PCM_Laan @RensHammie @bruin_bas @JoostReek onlinelibrary.wiley.com/doi/…

Gas Evolution as a Tool to Study Reaction Kinetics Under Biomimetic Conditions

The progress of transition metal-catalysed bioorthogonal chemical reactions can be accurately monitored by measuring the gas evolution in time using a bubble counter. This protocol provides insight...

chemistry-europe.onlinelibrary.wiley.com
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Bas de Bruin retweeted
ISCR@chimie_ISCR6 Mar 2024
📍Catalysis: how to replace palladium with greener systems ➡️iscr.univ-rennes.fr/greener-… Congratulations👏 to the teams involved! #ISCR @CNRSchimie @CNRS_dr17 @RennesUniv @ENSCR @INSA_Rennes @bruin_bas @UvA_Amsterdam
CNRS Chimie@CNRSchimie6 Mar 2024
#chimie ⚗️ #ResultatScientifique 📕 🔎 l #Catalyse : comment remplacer le palladium par des systèmes plus verts Des catalyseurs à base de cobalt surpassent ses performances... 🤝 @chimie_ISCR @CNRS_dr17 @RennesUniv @ENSCR @INSA_Rennes ➡️ buff.ly/3wFTQyh
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Glad to share Henric's @HenricSteffen work @Ghadwal_Group on "N‐Heterocyclic Carbene Analogues of Wittig Hydrocarbon" great collaboration with @bruin_bas thanks to @AvHStiftung and @dfg_public #BehindtheScene: A story to tell but not in public😉😉 chemistry-europe.onlinelibra…
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Bas de Bruin retweeted
Matthijs Vlot@yomattie27 Feb 2024
Replying to @Dolfjansen @NS_online
@Dolfjansen @NS_online @Borvanzeeland
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Bas de Bruin retweeted
ARC CBBC@ARCCBBC26 Feb 2024
On 15 February, Felix de Zwart (@UvA_Amsterdam) successfully defended his thesis! Congratulations, and good luck with the rest of your career! 🎓 @FelixJdeZwart @bruin_bas
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