@KyleGPearce

Research Fellow - @ScottChemistry - @BathChem | Member of the RSC: Main Group Chemistry Group Commitee

Joined April 2012
  • Tweets3.4K
  • Following608
  • Followers1.1K
204Media
Kyle Pearce retweeted
Marcus Drover@marcuswdroverOct 22
🎇 Excited to share this one: "A Nickel-Capped Calcium Hydride: Implications for Diene Hydrometallation" now posted on ChemRxiv: lnkd.in/gPAdBCGa Here, we report the synthesis and comprehensive characterization of a molecular complex featuring a σ–[Ca–H–Ni] interaction!
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Kyle Pearce retweeted
KretschmerLab@KretschmerLabOct 19
🧪 We’re hiring! 🚀 Interested in low-valent Group 13 & first-row transition-metal chemistry? Join us at TU Chemnitz for a postdoc position in our @ERC_Research CoG project #AGILE! 🔗 tu-chemnitz.de/verwaltung/pe… Please repost and spread the word! 📢 #ChemistryJobs #Postdoc
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STRONTIUM POWER: Although this series follows the octet rule, only neutral Ph3N is stable. Ph3B is very resistant to double reduction. Only Ar3B.- radical anions are known. However, it had to surrender to strontium. @angew_chem doi.org/10.1002/anie.3220261
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A single-source precursor for mixed fuel gases!🔥Meet Mg[(CH₃)ZnH₃]—a hydride-rich organometallic that releases a mixture of #Hydrogen & #methane, at just 80 °C. A fundamental discovery that could open up practical applications! #energy #chemistry doi.org/10.1126/sciadv.aej26…
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Kyle Pearce retweeted
Crimmin Group@crimmingroupSep 22
We have an open 2-year research associate position in the group to work on heterometallic complexes and their applications in catalysis. Details here: jobs.ac.uk/job/DSZ858/resear…

Research Associate in Organometallic Chemistry at Imperial College London

jobs.ac.uk
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Another redox story with Ca/Zn system!
Kyle Pearce@KyleGPearceSep 9
Our latest cooperative Ca/Zn venture: ether activation and alkyl migration. Some fun labelling experiments and stellar DFT by @Morales_Chem and @clairemcmullin disclosed within (@angew_chem). onlinelibrary.wiley.com/doi/…

Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert‐Butoxide Formation

When treated with dialkyl ethers, [(BDI)Ca-μ-H-Zn(t-Bu)2(η6-C7H8)] (BDI = HC{C(Me)NDipp}2 initiates a sequence of twofold ether dealkylation and oxide sequestration as tert-butoxide in a process...

onlinelibrary.wiley.com
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📢 We’re hiring! The Stanford Chemistry Department is now actively conducting faculty searches (open area) - term to start on 9/1/2027: - Assistant Professor in Chemistry - Senior Faculty Position in Chemistry (Associate Professor or Professor) Learn more: chemistry.stanford.edu/news/…
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A couple of new pre-prints just out from the group. If you're interested in main group chemistry or the mechanisms of photoredox catalysis at least one of these should be of interest! chemrxiv.org/doi/abs/10.2643… chemrxiv.org/doi/abs/10.2643…

Dramatic Countercation Effects on PC•− Speciation, Stability and Reaction Mechanisms in Photoexci...

“Photoexcited radical redox” methods such as conPET and e-PRC have had a dramatic synthetic impact and led to many fascinating new chemical transformations, but their underlying mechanisms remain...

chemrxiv.org
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Kyle Pearce retweeted
Joe Goodall@JC_GoodallJul 23
Today we report on the mechanism of intermolecular deprotonation and decomposition of tin(II) amides, and highlight that this mechanism is thermally accessible for the well-known Sn(HMDS)2. Variation of the amide enables access to C(sp2)–H and C(sp3)–H activated products.
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Delighted to see that our latest contribution has been featured on the Front Cover of @green_rsc This recognition marks the last research article of the thesis of our brilliant PhD student @MarcosLopezAg A well-deserved reward! linkedin.com/showcase/sustai…
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Dat (@ng_tiendat) and Corinna's (@C_Czernetzki) joint study on ligand and metal specific outcomes of K reductions of flexible, extremely bulky NON-group 2 metal (inc. Be) complexes has appeared as a pre-print @ChemRxiv. tinyurl.com/y4t7srf4 #ozchem @AFOSR @arc_gov_au
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Kyle Pearce retweeted
Oriol Planas@uri_planasJul 1
Interested in the latest advances in main group metal redox catalysis?🔄 Now in @ChemEurope, covering key mechanistic concepts, recent breakthroughs, and future opportunities for sustainable catalysis. ⬇️ Check it out! ⬇️ chemistry-europe.onlinelibra…

Main Group Metals in Redox Catalysis

Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design...

chemistry-europe.onlinelibrary.wiley.com
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Joe (@josephmparr) and co's work on using the normally inert NMR standard, TMS, as a ligand towards very Lewis acidic, neutral Ca and Sr complexes, has appeared as a pre-print @ChemRxiv. tinyurl.com/mr3sfccr. See the Mg analogue here tinyurl.com/hv7refvy. #ozchem @AFOSR
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Kyle Pearce retweeted
Oriol Planas@uri_planasMay 13
Are you interested in main group metal redox catalysis? 🚨Check out our last preprint summarising recent developments in the area! chemrxiv.org/doi/full/10.264…

Main Group Metals in Redox Catalysis | ChemRxiv

Main group metal redox catalysis is no longer a curiosity; it is a credible challenger to transition-metal chemistry. Heavy p-block elements, once dismissed as redox-inert or limited to Lewis acid...

chemrxiv.org
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🔥Hot Paper in @angew_chem! Counterion control unlocks nucleophilic gallyl anions, enabling unsupported Ga–Au chemistry for NH₃ activation Work led by @hellen_videa in our group, in collaboration with @TobiKraemer and @keelan542 @geqo_rseq @CIQSO_UHU onlinelibrary.wiley.com/doi/…
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Kyle Pearce retweeted
Sandy Kilpatrick@sandykillaMay 6
🚨 I’m looking for a keen PhD student to join my group at @Leicesterchem as a Graduate Teaching Assistant (GTA). Project on Ti complexes for CO2 valorisation & sustainable materials. #organometallics #catalysis Full training provided. Deadline 22 June 2026 le.ac.uk/study/research-degr…
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Kyle Pearce retweeted
Andreu@antornaMay 4
Excited to share our latest work in Chem Eur J on the alkali-metal-base-catalyzed electrocyclizations! Congratulations to Mikaël for the fantastic work. Thanks to the @snsf_ch and everyone that helped us along the way! @unifrChemistry Read here: doi.org/10.1002/chem.71057
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Kyle Pearce retweeted
Joe Goodall@JC_GoodallMay 1
Proud that my first joint corresponding author, and #MyFirstChemSci is now online at @ChemicalScience. We report on a Rh(III) σ-alkane complex that is indefinitely stable in the solid-state, where the supporting ligand undergoes reversible C-H activation. pubs.rsc.org/en/Content/Arti…

The characterisation and reactivity of a Rhiii η1-σ-alkane complex and the role of a structurally...

A combined experimental and computational study on the single-crystal to single-crystal addition of H2 to [Rh(κ2-dtbpb)(NBD)][BArF4] [dtbpb = tBu2P(CH2)4Pt

pubs.rsc.org
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Kyle Pearce retweeted
Makoto Yamashita@makoto_BApr 30
Our latest paper on the anionic Al-V complex and its dissociation to the alumanyl anion is now online. Multiple‐Bonding and Lability: Study of an Anionic Vanadium Alumanyl onlinelibrary.wiley.com/doi/…

Multiple‐Bonding and Lability: Study of an Anionic Vanadium Alumanyl

An anionic vanadium alumanyl complex was synthesized and characterized. It showed a shorter V─Al bond than that of its neutral congener. A detailed analysis, combining experimental and theoretical...

onlinelibrary.wiley.com
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Kyle Pearce retweeted
Crimmin Group@crimmingroupApr 28
Zinc Redox Catalysis in the Photochemical Borylation of Fluorocarbons. New @ChemRxiv preprint from @yangwenbang0310 and the team. chemrxiv.org/doi/full/10.264…
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